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To remove paint from roof tiles, you can use a power washer and a specialized cleaner designed for removing paint from masonry surfaces. If this method does not work, you can also try using a pressure washer in combination with a homemade solution made from a gallon of hot water, 1/4 cup of trisodium phosphate, 1/4 cup of dishwashing liquid and 1/2 cup of bleach.
Be sure to wear safety gear when working with power washers and chemical solutions, and rinse the area thoroughly with clean water afterwards.